Ok, so here is a summary of how the ER20 & 25 grinder collets differ from standard collets
Here are the two collet holders with collets installed. ER20 on the left ER25 on the right. You can also see the grinder indexing flats in the photo.
You can see the unique nose shapes. Very small for small drills and large for large drills. These are 1/16 and 3/4 respectively.
Focussing in on the ER25 Grinder collets, you can see how the skirt on the 3/4 holder does not reach the holder ID. It is recessed way down inside the holder. If the collet were reversed, the collet retaining grove and closer taper would be compromised. The collet on the left is a standard collet that fits the grinder and any other ER25 collet set. The collet on the right is unique to the grinder.
The opposite applies to the smaller ER20 collet sizes. A standard ER20 1/8" collet looks like the top right collet from the rear and the top left collet from the front. To make it possible to firmly hold small drills in a reversed ER20 collet, the internal design shown in the bottom collet is modified.
Here is a closeup showing the rear of a standard 1/8 collet. You can see the clamping portion down inside. It is designed to hold 1/8 parts at the front of the collet, not the rear. Used in reverse, this collet would not hold a drill bit solidly. Hence the need for the specialized 1/8 collet at the bottom of the photo above.
To be clear, many of the larger size ER20 collets look like standard collets. So do many of the smaller ER25 Collets.
But buying collets individually isn't generally very economical.
As
@CWret pointed out above, there isn't much point in sharpening large drills with the grinder. They are easy to do by hand. Similarly, there isn't much point sharpening tiny drills when they can be purchased at quantities at low cost.
I think the grinder makes sense from 3/32 to 5/8. Even 3/4 is too big and sharpens with a funny geometry in the grinder.
I'm sure there are those who would say that 3/32 is on the small size - better to just buy them in bulk.